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Solid State Batteries

Image reference: Dobbins TA. Overview of the Structure–Dynamics–Function Relationships in Borohydrides for Use as Solid-State Electrolytes in Battery Applications. Molecules. 2021; 26(11):3239.

Since the commercial introduction of lithium-ion batteries, they have become the industry standard, powering everything from smartphones to electric cars.


However, as with any technology, there comes a point when we start hitting the limits of what's possible and need to look beyond for the next breakthrough. This seemingly unstoppable surge in demand for higher energy density, a longer lifespan, and increased safety in battery technology has given rise to what could be the next big thing in energy storage: Solid-State Batteries. 


But what are these solid-state batteries? Why are they seen as a game-changer in the world of rechargeable batteries? 

In a conventional Li-ion battery, the electrolyte is a liquid, and it presents several challenges, including safety issues, limited energy density, and a short lifespan. Solid-state batteries aim to address these issues by replacing the liquid electrolyte with a solid one. This solid electrolyte can be ceramic, glass, sulfides, or polymers and can conduct lithium ions from one electrode to the other. 


✔️The transition from liquid to solid electrolytes brings significant benefits:


-Enhanced Safety:

It eliminates the risk of leakage, which is a key safety concern with liquid electrolytes. Moreover, solid electrolytes are mainly non-flammable, significantly reducing the risk of explosions and fires, a problem that has plagued conventional Li-ion batteries.


-Increased Energy Density:

One of their most promising advantages is their potential for higher energy density. Solid-state batteries can potentially offer 2 to 3 times the energy density of traditional Li-ion batteries, unlocking new possibilities for applications.


-Longer Lifespan:

It also exhibits less degradation over time compared to liquid electrolytes, thus withstanding more charge-discharge cycles before their performance starts to deteriorate, effectively extending the lifespan of the battery.


✔️A look at few Challenges:


Despite these compelling advantages, the path to widespread adoption of solid-state batteries is not without challenges. 


-Manufacturing these batteries at scale presents significant challenges. The production process requires extremely clean and dry conditions, which can be expensive to implement.


-Furthermore, at present, the cost per kWh of solid-state batteries is relatively higher. However, as with most new technologies, costs are expected to come down as production processes are refined and economies of scale are realized.


-Interfacial instability between the solid electrolyte and electrodes is another issue that needs to be addressed. It can lead to the formation of dendrites that can cause a short circuit, potentially leading to a safety hazard.




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