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Writer's pictureBaba Mulani

Role of Electrolytes in Efficient Ion Transport in Li-ion Batteries


Image Reference :Halie1758, CC BY-SA 4.0 <https://lnkd.in/dGXvSM3B>,

One of the key components of a Li-ion battery is the electrolyte, which enables the flow of lithium ions between the anode and cathode during charge and discharge cycles. An electrolyte is a liquid or gel substance that contains ions and is used to conduct electricity. In a Li-ion battery, the electrolyte acts as a medium that allows the movement of lithium ions from the anode to the cathode and vice versa during charging and discharging.


The most commonly used electrolyte in Li-ion batteries is a mixture of organic solvents and lithium salts. The organic solvents used in Li-ion electrolytes are typically highly polar and have a low viscosity, which allows them to dissolve lithium salts and facilitate the movement of lithium ions. Lithium salts used in Li-ion electrolytes typically include lithium hexafluorophosphate (LiPF6), lithium tetrafluoroborate (LiBF4), and lithium perchlorate (LiClO4). These salts dissociate in the organic solvent to form free lithium ions, which are then transported between the anode and cathode.


In addition to organic solvents and lithium salts, Li-ion electrolytes may also contain other additives such as flame retardants, stabilizers, and conductive agents. Flame retardants are used to reduce the risk of battery fires, while stabilizers help to prevent the decomposition of the electrolyte over time. Conductive agents such as carbon black may be added to improve the conductivity of the electrolyte.

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