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Writer's pictureBaba Mulani

Lithium Brine: A Promising Source for Sustainable Lithium Extraction



Lithium is a critical component of lithium-ion batteries, which power a wide range of devices, from smartphones to electric vehicles. One of the most promising sources of lithium is lithium brine, a saltwater solution found in underground reservoirs. Lithium brine extraction offers several advantages compared to traditional hard rock mining.


Lithium is a critical component of lithium-ion batteries, which power a wide range of devices, from smartphones to electric vehicles. One of the most promising sources of lithium is lithium brine, a saltwater solution found in underground reservoirs. Lithium brine extraction offers several advantages compared to traditional hard rock mining.


What is Lithium Brine?


Lithium brine is a saltwater solution that contains high concentrations of lithium, along with other valuable elements such as potassium, magnesium, and boron. These brines are typically found in underground reservoirs, often beneath salt flats or dried lake beds. The largest known lithium brine deposits are located in the "Lithium Triangle," a region spanning parts of Argentina, Bolivia, and Chile. The high concentration of lithium in these brines makes them an attractive source for lithium extraction.


Lithium Brine Extraction Process:


The process of extracting lithium from brine involves several steps:


  1. Pumping: The lithium-rich brine is pumped from underground reservoirs to the surface, where it is collected in a series of evaporation ponds.

  2. Evaporation: The brine is left to evaporate under the sun's heat for several months, causing water to evaporate and leaving behind a concentrated solution of lithium and other salts.

  3. Chemical treatment: Once the brine has reached the desired concentration, it is treated with various chemicals to separate the lithium from other elements. This process typically involves the addition of soda ash (sodium carbonate) to precipitate lithium carbonate, which can then be filtered and removed from the solution.

  4. Lithium carbonate purification: The lithium carbonate is further purified through a series of washing and filtering steps, followed by the removal of residual impurities using a combination of chemical treatments and precipitation techniques. The final product is high-purity lithium carbonate, which is a white, crystalline powder.

  5. Conversion to lithium hydroxide: For certain battery applications, the lithium carbonate is further processed into lithium hydroxide, a compound with higher energy density and better thermal stability. This conversion involves treating the lithium carbonate with caustic soda (sodium hydroxide) and then filtering and washing the resulting lithium hydroxide.


Challenges of lithium brine extraction:


  1. Lengthy extraction process: The evaporation step in lithium brine extraction can take several months, making it a slow and time-consuming process.

  2. Water consumption: Lithium brine extraction requires significant amounts of water, particularly for the evaporation ponds. This can lead to water scarcity issues in arid regions, such as the Lithium Triangle, where water resources are already limited.

  3. Potential environmental risks: Although lithium brine extraction has a lower environmental impact compared to hard rock mining, it still poses some risks.


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