An internal short in a lithium-ion battery is a silent problem living within, capable of causing significant damage. This short, essentially an unintended electrical connection between the anode and cathode, can bypass the external circuit, resulting in a quick energy discharge.
What causes Internal Shorts?:
- Manufacturing defects: Tiny metallic contaminants may find their way inside the cell, forming current pathways.
- Mechanical damage : Accidents or drops may cause damage like punctures or crushing of the pack/cell, resulting in the internal layers coming into contact.
- Electrochemical processes: As the battery ages, metallic lithium dendrites can sprout from the anode, reaching towards the cathode, which can cause a short if they bridge the gap.
- Overcharging: Exceeding recommended charging limits can damage the separator, bringing the anode and cathode into contact.
- Thermal abuse: Exposing the battery to high temperatures may compromise the separator, inviting direct anode-cathode contact.
Effects of Internal Shorts:
- Rapid heat generation is common, significantly raising the cell's temperature.
- In severe scenarios, this heat could start a chain reaction known as "thermal runaway," wherein escalating temperatures degrade the electrolyte, potentially leading to explosions or fires.
- There's the risk of the battery swelling, which might rupture its casing.
- Detrimental effects include hampered performance and a shortened battery lifespan.
Detecting Internal Shorts in Battery Packs:
1) Using the Battery Management System (BMS):
1.1) Voltage Monitoring: A sharp drop in voltage can be a telltale sign. The BMS carefully checks cell voltages, raising alarms or initiating safeguarding actions when needed.
1.2) Temperature Monitoring: Anomalies in temperature, especially sudden spikes, could be indicative of internal shorts.
1.3) Balancing: Cells that aren't aligning with the BMS's balancing functions might contain an internal problem.
2) External Sensors: Infrared or thermal cameras can spot hotspots in a battery pack, potentially pointing towards internal shorts.
3) Online Monitoring Systems: Ideal for large battery installations and in EVs, these systems continually monitor battery parameters, with built-in algorithms that detect or predict anomalies, including internal shorts.
While internal shorts in lithium-ion batteries are a major concern, modern technology equips us with a set of tools to detect and manage them.